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31 October 2024 Detection of florpyrauxifen-benzyl residues in tree nut crop leaves after simulated drift treatment
Deniz Inci, Bradley D. Hanson, Kassim Al-Khatib
Author Affiliations +
Abstract

Rice herbicide drift poses a significant challenge in California, where rice fields are near almond, pistachio, and walnut orchards. This research was conducted as part of a stewardship program for a newly registered rice herbicide and specifically aimed to compare the onset of foliar symptoms resulting from simulated florpyrauxifen-benzyl drift with residues in almond, pistachio, and walnut leaves at several time points after exposure. Treatments were applied to one side of the canopy of 1- and 2-yr-old trees at 1/100X and 1/33X of the florpyrauxifen-benzyl rice field use rate of 29.4 g ai ha-1 in 2020 and 2021. Symptoms were observed 3 d after treatment (DAT) for pistachio and 7 DAT for almond and walnut, with peak severity at approximately 14 DAT. While almond and walnut symptoms gradually dissipated throughout the growing season, pistachio still had symptoms at leaf out in the following spring. Leaf samples were randomly collected from each tree for residue analysis at 7, 14, and 28 DAT. At 7 DAT with the 1/33X rate, almond, pistachio, and walnut leaves had florpyrauxifen-benzyl at 6.06, 5.95, and 13.12 ng g–1 fresh weight (FW) leaf, respectively. By 28 DAT, all samples from all crops treated with the 1/33X drift rate had florpyrauxifen-benzyl at less than 0.25 ng g–1 FW leaf. At the 1/100X rate, pistachio, almond, and walnut residues were 1.78, 2.31, and 3.58 ng g–1 FW leaf at 7 DAT, respectively. At 28 DAT with the 1/100X rate, pistachio and almond samples had florpyrauxifen-benzyl at 0.1 and 0.04 ng g–1 FW leaf, respectively, but walnut leaves did not have detectable residues. Together, these data suggest that residue analysis from leaf samples collected after severe symptoms may substantially underestimate actual exposure due to the relatively rapid dissipation of florpyrauxifen-benzyl in nut tree foliage.

Nomenclature: Florpyrauxifen-benzyl; almond, Prunus dulcis (Mill.) D.A. Webb; pistachio, Pistacia vera L.; rice, Oryza sativa L.; walnut, Juglans regia L.

Deniz Inci, Bradley D. Hanson, and Kassim Al-Khatib "Detection of florpyrauxifen-benzyl residues in tree nut crop leaves after simulated drift treatment," Weed Technology 38(1), 1-7, (31 October 2024). https://doi.org/10.1017/wet.2024.52
Received: 7 May 2024; Accepted: 8 August 2024; Published: 31 October 2024
KEYWORDS
Auxinic herbicide
herbicide residue
Off-target movement
quantification
residue analysis
symptomology
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